Ummmm.... no. That's REPLAYING old Hands where all the cards are known.
When you are playing live (at least at any of the legit sites), the data about your opponents' cards is not being sent to your computer - encrypted or not. It's held on the server side. All you are sent is your information. So, barring hacking into the poker site's servers or instaling a web cam in your opponents' houses (GL with that), there is no way for you to access their hole cards.
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